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As of April 2016, The database that stores works on A03 does not allow emoji. If you try to add an emoji it will end your story there. Any words after the emoji? Poof. Gone. This is a known, if poorly advertised, issue with the archive.
There are some workarounds; you can find them in: How to Make iOS Text messages on A03. But here? Here is for ALL THE EMOJI*.
10 chapters of emoji tables, each with the HTML for putting the emoji into your work and the CSS for putting it into your workskin. Copy-Paste baby. Copy-Paste.
*Does not contain the 2016 Unicode release. You'll have to come up with the code for pickle yourselves.
(Note, because this is 10 chapters of emoji tables, here is a link to the Index Tables (chapter 1) to speed up load times and reduce confusion if you have preferences set to "entire work.")
- Part 11 of AO3 Work Skins/Tutorials