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Toph does not need anyone, certainly not the whiny Avatar or his bossy friend. Thank you very much, she's totally fine on her own. Zuko is sick of the Earth Kingdom and he just wants to go home. He really shouldn't stop when he witnesses some thugs threatening another stray kid, but he does. The chance encounter changes everything.
S2 AU - where Toph and Zuko run into each other mid-Chase and end up going on a field trip together. (I upped the rating to T for some mild cussing - just to be on the safe side).