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Completely without allies after Dean disappears, Sam decides desperate times call for desperate measures and takes a job working for Crowley, developing a new version of Dick Roman's "vamptonite" that will work on all monsters. It seems like a win-win situation - Sam becomes a more efficient hunter than ever before, and Crowley takes out his competition for earthly dominance. But during his work Sam meets a man who reminds him of Dean, and the more time they spend together the less certain Sam is that he's doing the right thing. Once he finally discovers a way to get Dean out of Purgatory, Sam is forced to decide how far he’s willing to go to get the one thing he’s always wanted.