This is more about Loki and exploring his character than shipping
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Repression of a traumatic childhood incident leads Loki down a destructive, violent path. Eventually, Thor learns the truth about what really happened and takes pity on Loki, rescuing him from brutal Asgardian justice and bringing him back to Earth. He doesn't plan to let his brother off the hook for his crimes, but he knows he'll be destroyed on Asgard. This unsettles the Avengers, with the exception of Natasha, who knows the value of second chances.